'Anti-Wacker'-type hydroalkoxylation of diynes catalyzed by palladium(0)

被引：38

作者：

Camacho, DH ^{[1
]}

Saito, S ^{[1
]}

Yamamoto, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 06期

关键词：

D O I：

10.1016/S0040-4039(01)02318-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The regioselective trans addition of acidic alcohols to conjugated diynes via a Pd(0)-diyne intermediate to give the alkoxylated enyne product, illustrates the first catalytic report involving electrophilic addition to unsaturated bonds by Pd(0). (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1085 / 1088

页数：4

共 22 条

[11] STEREOSELECTIVE ADDITION OF ALCOHOL TO ALKYNE CATALYZED BY DICATIONIC PLATINUM AND PALLADIUM COMPLEXES [J].

KATAOKA, Y ;

MATSUMOTO, O ;

OHASHI, M ;

YAMAGATA, T ;

TANI, K .

CHEMISTRY LETTERS, 1994, (07) :1283-1284

[12] Salt-free C-C coupling reactions of arenes:: palladium-catalyzed telomerization of phenols [J].

Krotz, A ;

Vollmüller, F ;

Stark, G ;

Beller, M .

CHEMICAL COMMUNICATIONS, 2001, (02) :195-196

[13] DOUBLE SILYLATION OF 1,4-BIS(TRIMETHYLSILYL)BUTADIYNE WITH DISILANES USING A PALLADIUM CATALYST [J].

KUSUMOTO, T ;

HIYAMA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (11) :3103-3110

[14] TRANSITION METAL-CARBON BONDS .24. ALKENYL-PLATINUM AND ALLENYL-PLATINUM(II) AND ALKENYL-PALLADIUM(II) COMPLEXES [J].

MANN, BE ;

SHAW, BL ;

TUCKER, NI .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (16) :2667-&

[15] The first synthesis of 4-trifluoromethyl-2H-pyrans by palladium-catalyzed cyclization of (E)-3-alkynyl-3-trifluoromethyl allylic alcohols [J].

Qing, FL ;

Gao, WZ .

TETRAHEDRON LETTERS, 2000, 41 (40) :7727-7730

[16] Platinum(0)-enyne complexes: The platinum analogue of an intermediate in the palladium(0)-catalyzed benzannulation of conjugated enynes [J].

Saito, S ;

Tando, K ;

Kabuto, C ;

Yamamato, Y .

ORGANOMETALLICS, 2000, 19 (18) :3740-3743

[17] INTERACTION OF (PH3P)4PT WITH ALKYNYLVINYL TRIFLATES - STEREOCHEMISTRY AND MECHANISM OF FORMATION OF SIGMA-ENYNYL AND SIGMA-BUTATRIENYL CATIONIC PLATINUM(II) COMPLEXES [J].

STANG, PJ ;

DATTA, AK .

ORGANOMETALLICS, 1989, 8 (04) :1024-1029

[18] PD-CATALYZED CYCLOISOMERIZATION TO 1,2-DIALKYLIDENECYCLOALKANES .2. ALTERNATIVE CATALYST SYSTEM [J].

TROST, BM ;

ROMERO, DL ;

RISE, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (10) :4268-4278

[19] PALLADIUM CATALYZED SYNTHESIS OF HETEROCYCLES [J].

UTIMOTO, K .

PURE AND APPLIED CHEMISTRY, 1983, 55 (11) :1845-1852

[20] VICINAL C,H SPIN COUPLING IN SUBSTITUTED ALKENES - STEREOCHEMICAL SIGNIFICANCE AND STRUCTURAL EFFECTS [J].

VOGELI, U ;

PHILIPSBORN, WV .

ORGANIC MAGNETIC RESONANCE, 1975, 7 (12) :617-627

← 1 2 3 →