Palladium-catalyzed arylation of butadiynes

被引:32
作者
Dyker, G
Borowski, S
Henkel, G
Kellner, A
Dix, I
Jones, PG
机构
[1] Univ Duisburg, Fachbereich 6, Inst Synth Chem, D-47048 Duisburg, Germany
[2] Tech Univ Braunschweig, Inst Organ Chem, D-38106 Braunschweig, Germany
[3] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
关键词
arylation; butadiynes; butatrienes; domino processes; palladium catalysis;
D O I
10.1016/S0040-4039(00)01474-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Diarylbutadiynes 1 undergo a palladium-catalyzed coupling reaction with aryl halides 2 to give tetraarylbutatrienes 3, which may further react to benzofulvenes 6 depending on the reaction temperature and the type of aryl groups. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:8259 / 8262
页数:4
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