Catalytic oxidation of aniline by aqueous hydrogen peroxide in the presence of some heteropolyoxometalates

被引：32

作者：

Alizadeh, MH

Tayebee, R ^{[1
]}

机构：

[1] Sabzevar Univ, Dept Chem, Sabzevar 397, Iran

[2] Ferdowsi Univ Mashhad, Dept Chem, Mashhad, Iran

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2005年 / 16卷 / 01期

关键词：

oxidation; polyoxometalates; aniline;

D O I：

10.1590/S0103-50532005000100017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aniline was selectively converted into the corresponding nitrosobenzene and nitrobenzene by oxidation with 30% aqueous hydrogen peroxide. The reaction was catalyzed by various heteropolyoxometalates, at room temperature, in dichloromethane under two-phase conditions. Findings show that H3PW12O40 is the best catalyst in the oxidation of aniline. Na3PW9Mo3O40 and K4SiW9Mo2O39 also displayed high reactivity in the oxygenation system. Phase transfer agents and temperature increase also contribute to the efficiency of the oxidation.

引用

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页码：108 / 111

页数：4

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