Synthesis and structure of a triptycene-based nanosized molecular cage

被引:109
作者
Zhang, Chun [1 ]
Chen, Chuan-Feng [1 ]
机构
[1] Chinese Acad Sci, Ctr Chem Biol, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China
关键词
D O I
10.1021/jo7017526
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[Graphics] A triptycene-based nanosized molecular cage was designed and efficiently synthesized by Eglington-Glaser coupling reaction, and its structure was determined by NMR, MS spectrometry and X-ray analysis. Moreover, it was found that the cage molecules could pack into a microporous structure in the solid state and 1,3,5-trimethylbenzene molecules were located in the channels.
引用
收藏
页码:9339 / 9341
页数:3
相关论文
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