Synthesis of anthropomorphic molecules: The NanoPutians

被引:72
作者
Chanteau, SH
Tour, JM
机构
[1] Rice Univ, Dept Chem, Houston, TX 77005 USA
[2] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA
关键词
D O I
10.1021/jo0349227
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Described here are the synthetic details en route to an array of 2-nm-tall anthropomorphic molecules in monomeric, dimeric, and polymeric form. These anthropomorphic figures are called, as a class, NanoPutians. Using tools of chemical synthesis, the ultimate in designed miniaturization can be attained while preparing the most widely recognized structures: those that resemble humans.
引用
收藏
页码:8750 / 8766
页数:17
相关论文
共 20 条
[1]   Reaction of vinyl epoxides with palladium-switchable bisnucleophiles:: Synthesis of carbocycles [J].
Castaño, AM ;
Méndez, M ;
Ruano, M ;
Echavarren, AM .
JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (02) :589-593
[2]  
CHAN TH, 1983, SYNTHESIS-STUTTGART, P203
[3]   Arts and sciences unite in Nanoput: Communicating synthesis and the nanoscale to the layperson [J].
Chanteau, SH ;
Ruths, T ;
Tour, JM .
JOURNAL OF CHEMICAL EDUCATION, 2003, 80 (04) :395-400
[4]   A modified Sandmeyer methodology and the synthesis of (+/-)-convolutamydine A. [J].
Garden, SJ ;
Torres, JC ;
Ferreira, AA ;
Silva, RB ;
Pinto, AC .
TETRAHEDRON LETTERS, 1997, 38 (09) :1501-1504
[5]   Preparation of titanated alkoxyallenes from 3-alkoxy-2-propyn-1-yl carbonates and (η2-propene)Ti(O-i-Pr)2 as an efficient ester homoaldol equivalent [J].
Hanazawa, T ;
Okamoto, S ;
Sato, F .
ORGANIC LETTERS, 2000, 2 (15) :2369-2371
[6]  
HAROLD H, 1985, J ORG CHEM, V50, P3104
[7]  
HAROLD H, 1991, J ORG CHEM, V56, P5630
[8]   NEW APPROACH TO LYTHRACEAE ALKALOIDS - TOTAL SYNTHESIS OF (+/-)-VERTALINE [J].
HART, DJ ;
KANAI, K .
JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (08) :1555-1560
[9]   REPRESENTATION IN CHEMISTRY [J].
HOFFMANN, R ;
LASZLO, P .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (01) :1-16
[10]   Double radical cyclization/beta-fragmentation of acyclic omega-yne vinyl sulfides. Synthesis of 3-vinyldihydrothiophene and dihydrothiopyran derivatives. A new example of a 5-endo-trig radical cyclization [J].
Journet, M ;
Rouillard, A ;
Cai, DW ;
Larsen, RD .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (25) :8630-8631