One-step preparation of [RuCp*(η6-arene)]+ sandwich complexes

被引：29

作者：

Schmid, A ^{[1
]}

Piotrowski, H ^{[1
]}

Lindel, T ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 12期

关键词：

ruthenium; sandwich complexes; NMR spectroscopy; synthetic methods;

D O I：

10.1002/ejic.200200579

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In a single step, several variously functionalized [RuCp* (eta(6)-arene)](+) sandwich complexes have been prepared starting from RuCl3.xH(2)O in yields ranging from 35 to 80%, referring to ruthenium. The protocol covers the preparation of valuable [RuCp*](+)-complexed amino acids. In comparative experiments starting from the oligomer [RuCp* Cl-2](n) and using methanol/methanolate as the reducing agent, the formation of undesired side products was observed, resulting from nucleophilic substitution at the o-chloroanisole complex and from methoxylation of the Cp* ligand. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

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页码：2255 / 2263

页数：9

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