Electrosynthesised Metal (Ni, Fe, Co) Oxide Films on Single-Walled Carbon Nanotube Platforms and Their Supercapacitance in Acidic and Neutral pH Media

被引:26
作者
Adekunle, Abolanle S. [1 ]
Ozoemena, Kenneth I. [1 ,2 ]
机构
[1] Univ Pretoria, Dept Chem, ZA-0002 Pretoria, South Africa
[2] CSIR, Energy & Proc Unit, ZA-0001 Pretoria, South Africa
基金
新加坡国家研究基金会;
关键词
SWCNT-metal oxide nanocomposites; Electrodeposition; Supercapacitance; Cyclic voltammetry; Impedance spectroscopy; ELECTROCHEMICAL PROPERTIES; ELECTRODE MATERIAL; NICKEL; POLYPYRROLE; COMPOSITE; MICROSTRUCTURE; PERFORMANCE; BEHAVIOR; CHARGE;
D O I
10.1002/elan.201000597
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Supercapacitive properties of Single-walled carbon nanotubes/metal oxides nanocomposites (SWCNT-MO where M=Ni, Fe, Co) have been described. The SWCNT-MO nanocomposites was confirmed with SEM, EDX and XPS techniques. Supercapacitive properties of the modified electrodes in H2SO4 and Na2SO4 electrolytes was investigated using cyclic voltammetry (CV), galvanostatic constant current charge-discharge (CD) and the electrochemical impedance spectroscopy (EIS) techniques. SWCNT-NiO nanocomposite modified electrodes gave better supercapacitive performance with a specific capacitance of 186 mF cm(-2) (or 928 F g(-1)). This value compared quite favourably and even higher than values hitherto reported in several literature.
引用
收藏
页码:971 / 979
页数:9
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