The use of sulfur ylides in the synthesis of substituted indoles

被引：24

作者：

Kennedy, AR ^{[1
]}

Taday, MH ^{[1
]}

Rainier, JD ^{[1
]}

机构：

[1] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 15期

关键词：

D O I：

10.1021/ol0162320

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] This letter describes the insertion of rhodium carbenoids into thioindoles, C-10 thioindoles undergo fragmentation-coupling reactions when exposed to rhodium carbenoids. In an analogous fashion, ketoester- and malonate-substituted carbenoids have been found to insert into C-2 thioindoles, In contrast, vinylogous carbenoids were found to alkylate C-2 thioindoles at C-3.

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页码：2407 / 2409

页数：3

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