Molecular Catalysis in a Fuel Cell

被引：35

作者：

Matsumoto, Takahiro ^{[1
]}

Kim, Kyoungmok ^{[1
]}

Ogo, Seiji ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Nishi Ku, Fukuoka 8190395, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 47期

关键词：

fuel cells; hydrogen; molecular catalysis; oxygen; H-2; COMPLEX; CATHODE;

D O I：

10.1002/anie.201104498

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Jack of all trades: A fuel cell based on a single molecular catalyst (see picture) uses a [NiFe]hydrogenase mimic to catalyze the oxidation of H 2. Crucially, the catalyst is also active for the reduction of O 2, allowing the construction of a fully functional fuel cell. This molecular catalyst can function both in solid and solution phases, allowing precise observation of the mechanism. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11202 / 11205

页数：4

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