The (butadiene) metal complex/B(C6F5)3 pathway to homogeneous single component Ziegler-Natta catalyst systems

被引：57

作者：

Erker, G ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 13期

关键词：

D O I：

10.1039/b208898n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Lewis acid B(C6F5)(3) adds to a variety of (butadiene) metal systems to yield zwitterionic complexes that are active homogeneous Ziegler - Natta type olefin polymerization catalysts. The new compounds have been useful in experimental studies gaining information about details of the carbon - carbon coupling reactions at these often fast and selective catalyst systems.

引用

页码：1469 / 1476

页数：8

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