Co-sensitized DSCs: dye selection criteria for optimized device Voc and efficiency

被引：59

作者：

Clifford, John N. ^{[1
]}

Forneli, Amparo ^{[1
]}

Chen, Huajie ^{[2
]}

Torres, Tomas ^{[3
]}

Tan, Songting ^{[2
]}

Palomares, Emilio ^{[1
,4
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Xiangting Univ, Coll Chem, Xiangting 411105, Peoples R China

[3] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

[4] ICREA, E-08012 Barcelona, Spain

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 06期

关键词：

NANOCRYSTALLINE TIO2 FILMS; SOLAR-CELLS; ORGANIC-DYES; COSENSITIZATION; ENERGY; DONOR;

D O I：

10.1039/c0jm03661g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Co-sensitization of nanocrystalline TiO2 with the organic dye D2 and the zinc phthalocyanine dye TT1 improves light harvesting, J(sc) and efficiency of DSC devices. However, the V-oc of the co-sensitized cell is markedly inferior (similar to 130 mV) when compared to the reference device made with D2 only. We discuss the implications of our results with regard to selection criteria for dyes for co-sensitized DSCs.

引用

页码：1693 / 1696

页数：4

共 23 条

[11] Increased light harvesting in dye-sensitized solar cells with energy relay dyes [J].

Hardin, Brian E. ;

Hoke, Eric T. ;

Armstrong, Paul B. ;

Yum, Jun-Ho ;

Comte, Pascal ;

Torres, Tomas ;

Frechet, Jean M. J. ;

Nazeeruddin, Md Khaja ;

Graetzel, Michael ;

McGehee, Michael D. .

NATURE PHOTONICS, 2009, 3 (07) :406-411

[12] Dye-sensitized solar cells consisting of dye-bilayer structure stained with two dyes for harvesting light of wide range of wavelength [J].

Inakazu, Fumi ;

Noma, Yusuke ;

Ogomi, Yuhei ;

Hayase, Shuzi .

APPLIED PHYSICS LETTERS, 2008, 93 (09)

[13]

Lee K, 2009, NAT MATER, V8, P665, DOI [10.1038/NMAT2475, 10.1038/nmat2475]

[14] Metal-Free Organic Dyes for Dye-Sensitized Solar Cells: From Structure: Property Relationships to Design Rules [J].

Mishra, Amaresh ;

Fischer, Markus K. R. ;

Baeuerle, Peter .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (14) :2474-2499

[15] Iodide electron transfer kinetics in dye-sensitized nanocrystalline TiO2 films [J].

Montanari, I ;

Nelson, J ;

Durrant, JR .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (47) :12203-12210

[16] Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers [J].

Nazeeruddin, MK ;

De Angelis, F ;

Fantacci, S ;

Selloni, A ;

Viscardi, G ;

Liska, P ;

Ito, S ;

Bessho, T ;

Grätzel, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (48) :16835-16847

[17] Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells [J].

Nazeeruddin, MK ;

Péchy, P ;

Renouard, T ;

Zakeeruddin, SM ;

Humphry-Baker, R ;

Comte, P ;

Liska, P ;

Cevey, L ;

Costa, E ;

Shklover, V ;

Spiccia, L ;

Deacon, GB ;

Bignozzi, CA ;

Grätzel, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (08) :1613-1624

[18] A LOW-COST, HIGH-EFFICIENCY SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS [J].

OREGAN, B ;

GRATZEL, M .

NATURE, 1991, 353 (6346) :737-740

[19] A solar cell sensitized with three different dyes [J].

Perera, VPS ;

Pitigala, PKDDP ;

Senevirathne, MKI ;

Tennakone, K .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 85 (01) :91-98

[20] Optimizing dyes for dye-sensitized solar cells [J].

Robertson, N .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (15) :2338-2345

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