Direct observation of t2g orbital ordering in magnetite

被引:79
作者
Schlappa, J. [1 ]
Schuessler-Langeheine, C. [1 ]
Chang, C. F. [1 ]
Ott, H. [1 ]
Tanaka, A. [2 ]
Hu, Z. [1 ]
Haverkort, M. W. [1 ]
Schierle, E. [3 ]
Weschke, E. [3 ]
Kaindl, G. [3 ]
Tjeng, L. H. [1 ]
机构
[1] Univ Cologne, Inst Phys 2, D-50937 Cologne, Germany
[2] Hiroshima Univ, ADSM, Dept Quantum Matter, Higashihiroshima 7398530, Japan
[3] Free Univ Berlin, Inst Expt Phys, D-14195 Berlin, Germany
关键词
D O I
10.1103/PhysRevLett.100.026406
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Using soft-x-ray diffraction at the site-specific resonances in the Fe L(2,3) edge, we find clear evidence for orbital and charge ordering in magnetite below the Verwey transition. The spectra show directly that the (001/2) diffraction peak (in cubic notation) is caused by t(2g) orbital ordering at octahedral Fe(2+) sites and the (001) by a spatial modulation of the t(2g) occupation.
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页数:4
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