Solvent impregnated resins: Relation between impregnation process and polymer support morphology .1. Di-(2-ethylhexyl) dithiophosphoric acid

被引：38

作者：

Jerabek, K ^{[1
]}

Hankova, L ^{[1
]}

Strikovsky, AG ^{[1
]}

Warshawsky, A ^{[1
]}

机构：

[1] WEIZMANN INST SCI,DEPT ORGAN CHEM,IL-76100 REHOVOT,ISRAEL

来源：

REACTIVE & FUNCTIONAL POLYMERS | 1996年 / 28卷 / 02期

关键词：

polymer adsorbents; adsorption; solvent impregnated resins;

D O I：

10.1016/1381-5148(95)00082-8

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The relationship between polymer support morphology and adsorption of di-(2-ethylhexyl)dithiophosphoric acid (DEHTPA) from alcoholic solution has been studied. As polymer supports investigated are the conventional commercial polymer adsorbents Amberlite XAD-2 and XAD-4 and two microporous polymer adsorbents prepared by post-polymerization crosslinking of swollen chloromethylated gel-type and macroreticular copolymers of styrene and divinylbenzene. Their morphology has been studied by nitrogen adsorption/desorption method. It was found that in the adsorption process DEHTPA fills the pore space gradually from the smallest pores up to pores with a diameter of approximately 10 nm.

引用

页码：201 / 207

页数：7

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