Solvent impregnated resin (STR) containing dialkyl dithiophosphoric acid on Amberlite XAD-2: Extraction of copper and comparison to the liquid-liquid extraction

被引：54

作者：

Strikovsky, AG

Jerabek, K

Cortina, JL

Sastre, AM

Warshawsky, A

机构：

[1] WEIZMANN INST SCI,DEPT ORGAN CHEM,IL-76100 REHOVOT,ISRAEL

[2] UNIV POLITECN CATALUNYA,DEPT ENGN QUIM,E-08028 BARCELONA,SPAIN

[3] INST CHEM PROC FUNDAMENTALS,CR-16502 PRAGUE 6,CZECH REPUBLIC

[4] WEIZMANN INST SCI,FEINBERG GRAD SCH,IL-76100 REHOVOT,ISRAEL

来源：

REACTIVE & FUNCTIONAL POLYMERS | 1996年 / 28卷 / 02期

关键词：

metal extraction; solvent-impregnated resin; Amberlite XAD-2 polymer; di-(2-ethylhexyl) dithiophosphoric acid;

D O I：

10.1016/1381-5148(95)00060-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The extraction of Cu(II) from chloride solutions at 0.19 M Cl- ionic strength by solvent impregnated resins (SIR) containing di-(2-ethylhexyl) dithiophosphoric acid (DEHTPA) on the Amberlite XAD-2 polymeric support has been studied. The distribution of DEHTPA between the aqueous phase and the resin phase was determined as a function of both pH and loading of DEHTPA ligand (HL) on the resin, The Cu(II) extraction are presented as plots of log distribution coefficient versus pH and DEHTPA concentration in the resin phase. Graphical and computer analysis showed that the extraction of Cu(II) can be explained by the formation of metal complexes in the resin phase of CuCl2(HL)(8) and CuClL(HL)(8) composition with values of equilibrium extraction constants K' = 9.19 max 9.41 and K '' = 7.69 max 7.99, respectively.

引用

页码：149 / 158

页数：10

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