Annealing effects on the photovoltaic performance of all-conjugated poly(3-alkylthiophene) diblock copolymer-based bulk heterojunction solar cells

被引：57

作者：

He, Ming ^{[1
,2
]}

Han, Wei ^{[1
,3
]}

Ge, Jing ^{[2
]}

Yu, Weijie ^{[1
]}

Yang, Yuliang ^{[2
]}

Qiu, Feng ^{[2
]}

Lin, Zhiqun ^{[1
,3
]}

机构：

[1] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50010 USA

[2] Fudan Univ, Key Lab Mol Engn Polymers, Minist Educ, Dept Macromol Sci, Shanghai 200433, Peoples R China

[3] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA

来源：

NANOSCALE | 2011年 / 3卷 / 08期

基金：

美国国家科学基金会;

关键词：

SELF-ORGANIZATION; ORGANIC PHOTOVOLTAICS; SERIES RESISTANCE; POLYMER; MORPHOLOGY; NANOCOMPOSITES; SEPARATION; FILMS;

D O I：

10.1039/c1nr10293a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effects of thermal and solvent vapor annealing on the photovoltaic performance of a new class of all-conjugated poly(3-butylthiophene)-b-poly(3-hexylthiophene) diblock copolymer/PC71BM bulk heterojunction (BHJ) solar cells were scrutinized and theoretically analyzed using the single diode model combined with experimental measurements. The meanings of physical parameters in the model were elucidated in the context of crystalline order and phase separation to gain fundamental insight into the mechanism of annealing effects on the device performance of a new class of all-conjugated diblock copolymer-based BHJ solar cells.

引用

页码：3159 / 3163

页数：5

共 31 条

[11] Self-Assembly of All-Conjugated Poly(3-alkylthiophene) Diblock Copolymer Nanostructures from Mixed Selective Solvents [J].

He, Ming ;

Zhao, Lei ;

Wang, Jun ;

Han, Wei ;

Yang, Yuliang ;

Qiu, Feng ;

Lin, Zhiqun .

ACS NANO, 2010, 4 (06) :3241-3247

[12] Fabricating polythiophene into highly aligned microwire film by fast evaporation of its whisker solution [J].

He, Ming ;

Ge, Jing ;

Fang, Ming ;

Qiu, Feng ;

Yang, Yuliang .

POLYMER, 2010, 51 (10) :2236-2243

[13] A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene: fullerene solar cells [J].

Kim, Y ;

Cook, S ;

Tuladhar, SM ;

Choulis, SA ;

Nelson, J ;

Durrant, JR ;

Bradley, DDC ;

Giles, M ;

Mcculloch, I ;

Ha, CS ;

Ree, M .

NATURE MATERIALS, 2006, 5 (03) :197-203

[14] Origin of Radiation-Induced Degradation in Polymer Solar Cells [J].

Kumar, Ankit ;

Devine, Roderick ;

Mayberry, Clay ;

Lei, Bao ;

Li, Gang ;

Yang, Yang .

ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (16) :2729-2736

[15] High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends [J].

Li, G ;

Shrotriya, V ;

Huang, JS ;

Yao, Y ;

Moriarty, T ;

Emery, K ;

Yang, Y .

NATURE MATERIALS, 2005, 4 (11) :864-868

[16] Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology [J].

Ma, WL ;

Yang, CY ;

Gong, X ;

Lee, K ;

Heeger, AJ .

ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (10) :1617-1622

[17] Charge transport and photocurrent generation in poly (3-hexylthiophene): Methanofullerene bulk-heterojunction solar cells [J].

Mihailetchi, VD ;

Xie, HX ;

de Boer, B ;

Koster, LJA ;

Blom, PWM .

ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (05) :699-708

[18] Investigation of nanoscale morphological changes in organic photovoltaics during solvent vapor annealing [J].

Miller, Steve ;

Fanchini, Giovanni ;

Lin, Yun-Yue ;

Li, Cheng ;

Chen, Chun-Wei ;

Su, Wei-Fang ;

Chhowalla, Manish .

JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (03) :306-312

[19] DISTRIBUTED SERIES RESISTANCE EFFECTS IN SOLAR-CELLS [J].

NIELSEN, LD .

IEEE TRANSACTIONS ON ELECTRON DEVICES, 1982, 29 (05) :821-827

[20] The Role of Processing in the Fabrication and Optimization of Plastic Solar Cells [J].

Peet, Jeffrey ;

Senatore, Michelle L. ;

Heeger, Alan J. ;

Bazan, Guillermo C. .

ADVANCED MATERIALS, 2009, 21 (14-15) :1521-1527

← 1 2 3 4 →