Aerobic enantioselective alkene epoxidation by a chiral trans-dioxo(D4-porphyrinato) ruthenium(VI) complex

被引：105

作者：

Lai, TS

Zhang, R

Cheung, KK

Kwong, HL

Che, CM

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China

[2] City Univ Hong Kong, Dept Biol & Chem, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 15期

关键词：

D O I：

10.1039/a802009d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dioxoruthenium(VI) complex with a D-4-chiral porphyrin ligand has been prepared and characterized by spectroscopic methods and X-ray crystal analysis; the complex exhibits catalytic activity towards aerobic enantioselective epoxidation of prochiral alkenes with enantioselectivity up to 73% ee at an oxygen pressure of 8 atm.

引用

页码：1583 / 1584

页数：2

共 14 条

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