Improved transparency-nonlinearity trade-off with boroxine-based octupolar molecules

被引：64

作者：

Alcaraz, G

Euzenat, L

Mongin, O

Katan, C

Ledoux, I

Zyss, J

Blanchard-Desce, M

Vaultier, M

机构：

[1] Univ Rennes 1, CNRS, UMR 6510, Inst Chim, F-35042 Rennes, France

[2] ENS Cachan, CNRS, UMR 8537, Lab Photon Quant & Mol, F-94235 Cachan, France

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 22期

关键词：

D O I：

10.1039/b308664j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of octupolar molecules derived from the boroxine framework were designed and their optical nonlinearities were investigated by performing harmonic light scattering experiments in solution; the molecules were found to combine excellent transparency in the near UV-visible region (lambda(max) less than or equal to 280 nm) and significant first-order hyper-polarisabilities (up to beta(0) = 56 X 10(-30) esu).

引用

页码：2766 / 2767

页数：2

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