Photoinduced intramolecular electron transfer of carbazole trimer-[60]fullerene studied by laser flash photolysis techniques

被引：12

作者：

Konno, Takashi ^{[1
]}

El-Khouly, Mohamed E. ^{[2
,3
]}

Nakamura, Yosuke ^{[1
]}

Kinoshita, Keisuke ^{[1
]}

Araki, Yasuyuki ^{[2
,3
]}

Ito, Osamu ^{[2
,3
]}

Yoshihara, Toshitada ^{[1
]}

Tobita, Seiji ^{[1
]}

Nishimura, Jun ^{[1
]}

机构：

[1] Gunma Univ, Grad Sch Engn, Dept Chem & Chem Biol, Gunma 3768515, Japan

[2] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan

[3] Tanta Univ, Dept Chem, Fac Educ, Tanta, Egypt

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 04期

关键词：

D O I：

10.1021/jp076387a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photoinduced intramolecular events of newly synthesized bis(carbazole trimer)-C-60 adducts have been studied by laser flash photolysis techniques in polar and nonpolar solvents. For bis(tert-butyl-substituted carbazole trimer)-C-60 adduct, charge separation takes place via the excited singlet state of the C-60 moiety in polar solvents as revealed by the combination of the C-60-fluorescence quenching and transient absorptions of the radical ion pair. On the other hand, for bis(nonsubstituted carbazole trimer)-C-60 adduct, although charge separation takes place, the charge recombination is fast because of the lower electron-donor ability.

引用

页码：1244 / 1249

页数：6