A new chain-like cadmium(II) coordination polymer containing chains of water molecules

被引：16

作者：

Lin, X ^{[1
]}

Wang, YQ

Cao, R

Li, F

Bi, WH

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S0108270105007274

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title cadmium(II) polymer, catena-poly[[[ bis(4-aminopyridine-kappa N) aquacadmium(II)]-mu- 1,4-phenylenediacetato-kappa(4) O, O': O '', O'''] dihydrate], {[Cd(C10H8O4)(C5H6N2)(2)(H2O)] center dot 2H(2)O} (n), comprises one-dimensional wave-like chains, in which the Cd atom is coordinated by 1,4-phenylenediacetate and 4-aminopyridine molecules. The 1,4-phenylenediacetate ligands lie about inversion centres. Extensive hydrogen-bonding interactions between the chains lead to a three-dimensional structure. Free water molecules form chains in the structure.

引用

页码：M292 / M294

页数：3

共 6 条

[1] Puckered-boat conformation hexameric water clusters stabilized in a 2D metal-organic framework structure built from Cu(II) and 1,2,4,5-benzenetetracarboxylic acid [J].