A three-dimensional zinc(II) complex consisting of single metal centers and pentanuclear clusters bridged by 1,3,5-benzenetricarboxylate

被引：27

作者：

Li, XJ ^{[1
]}

Cao, R ^{[1
]}

Sun, DF ^{[1
]}

Yuan, DQ ^{[1
]}

Bi, WH ^{[1
]}

Li, X ^{[1
]}

Wang, YQ ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 694卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

zinc(II); 1,3,5-benzenetricarboxylic acid; hydrothermal reaction; double layer;

D O I：

10.1016/j.molstruc.2004.03.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrothermal reaction of 1,3,5-benzenetricarboxylic acid (H(3)btc), 2,2-bipyridine (bipy) and Zn(CH3CO2)(2)(.)2H(2)O gave rise to a three-dimensional polymer [Zn-3.5(mu(3)-OH)(btc)(2)(bipy)(2)(H2O)-H-.](n) (1). X-ray diffraction analysis reveals that 1 consists of pentanuclear metal clusters and single metal centers bridged by btc(3-). The pentanuclear zinc(II) clusters are connected by btc(3-) to give rise to a two-dimensional double layer motif. The neighbor double layers are further joined by single metal centers to create a three-dimensional porous framework. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：205 / 210

页数：6

共 38 条

[1] Hydroxylated nanoballs: synthesis, crystal structure, solubility and crystallization on surfaces [J].