A three-dimensional zinc(II) complex consisting of single metal centers and pentanuclear clusters bridged by 1,3,5-benzenetricarboxylate

被引：27

作者：

Li, XJ ^{[1
]}

Cao, R ^{[1
]}

Sun, DF ^{[1
]}

Yuan, DQ ^{[1
]}

Bi, WH ^{[1
]}

Li, X ^{[1
]}

Wang, YQ ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 694卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

zinc(II); 1,3,5-benzenetricarboxylic acid; hydrothermal reaction; double layer;

D O I：

10.1016/j.molstruc.2004.03.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrothermal reaction of 1,3,5-benzenetricarboxylic acid (H(3)btc), 2,2-bipyridine (bipy) and Zn(CH3CO2)(2)(.)2H(2)O gave rise to a three-dimensional polymer [Zn-3.5(mu(3)-OH)(btc)(2)(bipy)(2)(H2O)-H-.](n) (1). X-ray diffraction analysis reveals that 1 consists of pentanuclear metal clusters and single metal centers bridged by btc(3-). The pentanuclear zinc(II) clusters are connected by btc(3-) to give rise to a two-dimensional double layer motif. The neighbor double layers are further joined by single metal centers to create a three-dimensional porous framework. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：205 / 210

页数：6

共 38 条

[31] Two three-dimensional metal-organic frameworks from secondary building units of Zn8(OH)4(O2C-)12 and Zn2((OH)(O2C-)3:[Zn2(OH)(btc)]2(4,4′-bipy) and Zn2(OH)(btc)(pipe) [J].

Shi, Z ;

Li, GH ;

Wang, L ;

Gao, L ;

Chen, XB ;

Hua, J ;

Feng, SH .

CRYSTAL GROWTH & DESIGN, 2004, 4 (01) :25-27

[32] Blue photoluminescent zinc coordination polymers with supertetranuclear cores [J].

Tao, J ;

Tong, ML ;

Shi, JX ;

Chen, XM ;

Ng, SW .

CHEMICAL COMMUNICATIONS, 2000, (20) :2043-2044

[33] Syntheses and crystal structures of two novel zinc(II) coordination polymers [J].

Tao, J ;

Yin, X ;

Jiang, YB ;

Yang, LF ;

Huang, RB ;

Zheng, LS .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (14) :2678-2682

[34] Crown ethers as ancillary ligands in the assembly of silver(I) aggregates containing embedded acetylenediide [J].

Wang, QM ;

Mak, TCW .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (01) :44-50

[35] An unprecedented 8-fold interpenetrating diamondoid-like coordination polymer containing a Cu+4(RCO2)4 cluster as connecting node [J].

Wang, XS ;

Zhao, H ;

Qu, ZR ;

Ye, Q ;

Zhang, J ;

Xiong, RG ;

You, XZ ;

Fun, HK .

INORGANIC CHEMISTRY, 2003, 42 (19) :5786-+

[36] Syntheses and crystal structures of three novel coordination polymers:: [M2(bpy)(btc)(OH)]n (M = Ni,Co) and {[Co1.5(bpy)(btc)]•(H2O)2}n (bpy=2,2′-bipyridine, btc=1,3,5-benzenetricarboxylate) [J].

Wang, YQ ;

Cao, R ;

Sun, DF ;

Bi, WH ;

Li, X ;

Li, XJ .

JOURNAL OF MOLECULAR STRUCTURE, 2003, 657 (1-3) :301-309

[37] A cyclic octadecairon(III) complex, the molecular 18-wheeler [J].

Watton, SP ;

Fuhrmann, P ;

Pence, LE ;

Caneschi, A ;

Cornia, A ;

Abbati, GL ;

Lippard, SJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (24) :2774-2776

[38]

WENGER R, 2000, ANGEW CHEM INT EDIT, V112, P608

← 1 2 3 4 →