An unprecedented 8-fold interpenetrating diamondoid-like coordination polymer containing a Cu+4(RCO2)4 cluster as connecting node

被引：44

作者：

Wang, XS

Zhao, H

Qu, ZR

Ye, Q

Zhang, J ^{[1
]}

Xiong, RG

You, XZ

Fun, HK

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 19期

关键词：

D O I：

10.1021/ic0344620

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cu(I)(CH3CN)(4)BF4 with 4-pyridylacrylic acid (4-HPYA) affords an unprecedented 8-fold interpenetrating diamondoid-like coordination polymer network [CU(I)(3)(4-PYA)(2)(H2O)(BF4)] (1) with a CU4+(CO2)(4) cluster as connecting node. The interpenetration in metal coordination polymers is the highest degree ever found within diamondoid nets containing a cluster as connecting note. Its fluorescent property was also reported.

引用

页码：5786 / +

页数：4

共 56 条

[1]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[2]

2-Z

[3] Control of interpenetrating copper(I) adamantoid networks: Synthesis and structure of {[Cu(bpe)(2)]BF4}(n) [J].

Blake, AJ ;

Champness, NR ;

Chung, SSM ;

Li, WS ;

Schroder, M .

CHEMICAL COMMUNICATIONS, 1997, (11) :1005-1006

[4] The development of chiral metallacrowns into anion recognition agents and porous materials [J].

Bodwin, JJ ;

Cutland, AD ;

Malkani, RG ;

Pecoraro, VL .

COORDINATION CHEMISTRY REVIEWS, 2001, 216 :489-512

[5] Preparation of a chiral, 2-dimensional network containing metallacrown and copper benzoate building blocks [J].

Bodwin, JJ ;

Pecoraro, VL .

INORGANIC CHEMISTRY, 2000, 39 (16) :3434-+

[6]

Bourne SA, 2001, ANGEW CHEM INT EDIT, V40, P2111, DOI 10.1002/1521-3773(20010601)40:11<2111::AID-ANIE2111>3.0.CO

[7]

2-F

[8]

Carlucci L, 2002, CHEM-EUR J, V8, P1519, DOI 10.1002/1521-3765(20020402)8:7<1519::AID-CHEM1519>3.0.CO

[9]

2-5

[10] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].

Chen, BL ;

Eddaoudi, M ;

Hyde, ST ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2001, 291 (5506) :1021-1023

← 1 2 3 4 5 6 →