An unprecedented 8-fold interpenetrating diamondoid-like coordination polymer containing a Cu+4(RCO2)4 cluster as connecting node

被引：44

作者：

Wang, XS

Zhao, H

Qu, ZR

Ye, Q

Zhang, J ^{[1
]}

Xiong, RG

You, XZ

Fun, HK

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 19期

关键词：

D O I：

10.1021/ic0344620

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cu(I)(CH3CN)(4)BF4 with 4-pyridylacrylic acid (4-HPYA) affords an unprecedented 8-fold interpenetrating diamondoid-like coordination polymer network [CU(I)(3)(4-PYA)(2)(H2O)(BF4)] (1) with a CU4+(CO2)(4) cluster as connecting node. The interpenetration in metal coordination polymers is the highest degree ever found within diamondoid nets containing a cluster as connecting note. Its fluorescent property was also reported.

引用

页码：5786 / +

页数：4

共 56 条

[51] Opto-electronic multifunctional chiral diamondoid-network coordination polymer: bis{4-[2-(4-pyridyl)ethenyl]benzoato}zinc with high thermal stability [J].