[Ce(PSe4)4]9-:: a highly anionic Ce3+ selenophosphate coordination complex

被引：22

作者：

Chondroudis, K ^{[1
]}

Kanatzidis, MG ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 02期

基金：

美国国家科学基金会;

关键词：

cerium complexes; selenophosphate complexes; anionic complexes; crystal structures;

D O I：

10.1016/S1387-7003(98)00011-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ce with the basic polychalcophosphate flux Rb10P4Se25 yielded the quaternary selenophosphate compound Rb9Ce(PSe4)(4). The discrete [Ce(PSe4)(4)](9-) anion possesses the highest charge observed in a monometallic complex. The Ce3+ center is chelated by four bidentate [PSe4](3-) ligands so it achieves a dodecahedral coordination geometry, and the complex belongs to the dodecahedral sub-class Id (D-2d-(4) over bar 2m), according to the Hoard and Silverton notation. The UV-Vis, optical, IR spectroscopic and magnetism data for the compound are reported. (C) 1998 Elsevier Science S.A.

引用

页码：55 / 57

页数：3

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