Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand

被引:41
作者
Albrecht, M
Schmid, S
deGroot, M
Weis, P
Fröhlich, R
机构
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
[2] Univ Karlsruhe, Inst Phys Chem, D-76128 Karlsruhe, Germany
[3] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
关键词
D O I
10.1039/b309026d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral tetraketone ligands are obtained by Claisen-type condensation of 4-bromoacetophenone with the acetone ketal of L-tartraic acid diethylester and lead with gallium( III) or iron( III) ions in self-assembly processes to dinuclear helicate-type cryptands which are able to bind lithium cations.
引用
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页码:2526 / 2527
页数:2
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