Tetrabutylammonium and caesium salts of trinitromethane

被引：11

作者：

Bryan, JC ^{[1
]}

Burnett, MN ^{[1
]}

Gakh, AA ^{[1
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem & Analyt Sci, Oak Ridge, TN 37831 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198004491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two structures of the trinitromethane anion are reported. In tetra-n-butylammonium trinitromethanide, (C4H9)(4)N+. [C(NO2)(3)](-), the [C(NO2)(3)](-) anion adopts the commonly observed C-2v conformation, while in the Cs salt, caesium trinitromethanide, Cs+.[C(NO2)(3)](-), it adopts a distorted propeller conformation. Both stuctures exhibit cation-anion interactions that may influence the structure of the anion.

引用

页码：1229 / 1233

页数：5

共 15 条

[1] STRUCTURE OF 1,4-CUBANEDIYLDIAMMONIUM BIS(TRINITROMETHANIDE) [J].

AMMON, HL ;

CHOI, CS ;

DAMVARAPU, RS ;

IYER, S ;

ALSTER, J .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :295-298

[2] STRUCTURE OF 1-ADAMANTANYLAMMONIUM TRINITROMETHIDE [J].

AMMON, HL ;

CHOI, CS ;

BASHIRHASHEMI, A ;

MORIARTY, RM ;

KHOSROWSHAHI, JS .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :319-321

[3] THE ROLE PLAYED BY C-H...O AND C-H...N INTERACTIONS IN DETERMINING MOLECULAR PACKING AND CONFORMATION [J].

BERKOVITCHYELLIN, Z ;

LEISEROWITZ, L .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1984, 40 (APR) :159-165

[4]

Burnett M.N., 1996, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations

[5] ELECTRONIC-STRUCTURES OF TRIFLUOROMETHANE, TRICYANOMETHANE, AND TRINITROMETHANE AND THEIR CONJUGATE BASES [J].

CIOSLOWSKI, J ;

MIXON, ST ;

FLEISCHMANN, ED .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (13) :4751-4755

[6]

Enraf-Nonius, 1993, CAD 4 PC SOFTW VERS

[7]

GRIGOREVA NV, 1966, ZH STRUKT KHIM, V7, P278

[8]

HARMS K, 1995, XCAD4 PROGRAM LP COR

[9]

Liang P, 1941, ORG SYNTH, V21, P105

[10]

SCHERFISE KD, 1985, Z NATURFORSCH B, V40, P906

← 1 2 →