Tetrabutylammonium and caesium salts of trinitromethane

被引：11

作者：

Bryan, JC ^{[1
]}

Burnett, MN ^{[1
]}

Gakh, AA ^{[1
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem & Analyt Sci, Oak Ridge, TN 37831 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198004491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two structures of the trinitromethane anion are reported. In tetra-n-butylammonium trinitromethanide, (C4H9)(4)N+. [C(NO2)(3)](-), the [C(NO2)(3)](-) anion adopts the commonly observed C-2v conformation, while in the Cs salt, caesium trinitromethanide, Cs+.[C(NO2)(3)](-), it adopts a distorted propeller conformation. Both stuctures exhibit cation-anion interactions that may influence the structure of the anion.

引用

页码：1229 / 1233

页数：5