Experimental studies on the trans-influence of boryl ligands in square-planar platinum(II) complexes

被引：112

作者：

Braunschweig, Holger ^{[1
]}

Brenner, Peter ^{[1
]}

Mueller, Andreas ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Rais, Daniela ^{[1
]}

Uttinger, Katharina ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2007年 / 13卷 / 25期

关键词：

boron; boryl complexes; oxidative addition; platinum; trans-influence;

D O I：

10.1002/chem.200700539

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of platinum(II) boryl complexes of general formula trans- [((CyP)-P-3)(2)Pt(Br)(BX2)], including the rare dibromoboryl species trans[(Cy3P)(2)Pt(Br)(BBr2)], were synthesized by oxidative addition of the B-Br bond of a number of bromoboranes to [Pt(PCy3)(2)]. X-ray diffraction studies were performed on several such compounds. Comparison of the Pt-Br bond lengths allowed an empirical assessment of the trans-influence of different boryl ligands. A trans-influence scale was thus deduced and the results were compared with those previously computed for compounds of the type trans-[(Me3P)(2)Pt(Cl)(BX2)].

引用

页码：7171 / 7176

页数：6

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