Graphene-polyethylenedioxythiophene conducting polymer nanocomposite based supercapacitor

被引：199

作者：

Alvi, Farah ^{[2
]}

Ram, Manoj K. ^{[1
]}

Basnayaka, Punya A. ^{[3
]}

Stefanakos, Elias ^{[2
]}

Goswami, Yogi ^{[4
]}

Kumar, Ashok ^{[1
,3
]}

机构：

[1] Univ S Florida, Clean Energy Res Ctr, Tampa, FL 33620 USA

[2] Univ S Florida, Dept Elect Engn, Tampa, FL 33620 USA

[3] Univ S Florida, Dept Mech Engn, Tampa, FL 33620 USA

[4] Univ S Florida, Dept Chem & Biomed Engn, Tampa, FL 33620 USA

来源：

ELECTROCHIMICA ACTA | 2011年 / 56卷 / 25期

基金：

美国国家科学基金会;

关键词：

Graphene; Conducting polymer; PEDOT; Nanocomposite; Supercapacitor; Charge/discharge; ELECTRODE; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); PEDOT;

D O I：

10.1016/j.electacta.2011.08.024

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We present here the synthesis, characterization and application of graphene (G)-polyethylenedioxythiophene (PEDOT) nanocomposites as electrode material for supercapacitor applications. The G-PEDOT nanocomposite was synthesized using a chemical oxidative polymerization technique, and characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, FTIR spectroscopy, X-ray-diffraction, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV) techniques. The electrochemical charge/discharge characteristics of G-PEDOT nanocomposites were investigated in different electrolytic media, and the specific discharge capacitance was estimated to be 374 Farad/gram (F/gm). This manuscript presents the capacitance studies on supercapacitor G-PEDOT electrode with respect to stability of material, specific capacitance, electrical conductivity and specific charge/discharge properties of the supercapacitor electrodes. Our study has revealed that the G-PEDOT nanocomposite could be a transformable and viable electrode material for supercapacitor applications. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：9406 / 9412

页数：7

共 32 条

[31] Electrochemically and vapour grown electrode coatings of poly(3,4-ethylenedioxythiophene) doped with heteropolyacids [J].

White, AM ;

Slade, RCT .

ELECTROCHIMICA ACTA, 2004, 49 (06) :861-865

[32] Graphene/Polyaniline Nanofiber Composites as Supercapacitor Electrodes [J].

Zhang, Kai ;

Zhang, Li Li ;

Zhao, X. S. ;

Wu, Jishan .

CHEMISTRY OF MATERIALS, 2010, 22 (04) :1392-1401

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