Developments in the application of gas chromatography with atomic emission (plus mass spectrometric) detection

被引:19
作者
Van Stee, L. L. R. [1 ]
Brinkman, U. A. Th. [1 ]
机构
[1] Free Univ Amsterdam, Dept Analyt Chem & Appl Spect, NL-1081 HV Amsterdam, Netherlands
关键词
atomic emission detection; gas chromatography; mass spectrometry; organic analysis; applications;
D O I
10.1016/j.chroma.2007.10.031
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Capillary gas chromatography with atomic emission detection is a highly element-selective and sensitive detection technique for many nonmetal as well as metallic elements. A 3-5 order of magnitude element/carbon selectivity, compound-independent calibration and the possibility to calculate (partial) molecular formulae are some of the attractive features of the technique. In the present review, the emphasis is on real-life applications for non-metals such as sulphur, phosphor-us, nitrogen and the halogens, and on the potential of combined atomic emission/mass spectrometric detection. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:109 / 122
页数:14
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