Tuning the solubility of polymerized ionic liquids by simple anion-exchange reactions

被引：330

作者：

Marcilla, R

Blazquez, JA

Rodriguez, J

Pomposo, JA

Mecerreyes, D ^{[1
]}

机构：

[1] CIDETEC, Ctr Electrochem Technol, New Mat Dept Paseo Miramon, San Sebastian 20009, Spain

[2] Univ Basque Country, Polymer Sci & Technol Dept, San Sebastian 20018, Spain

[3] Univ Basque Country, Inst Polymer Mat POLYMAT, San Sebastian 20018, Spain

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2004年 / 42卷 / 01期

关键词：

polycations; ionic liquids; high performance polymers; polyelectrolytes; hydrophilic polymers;

D O I：

10.1002/pola.11015

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ionic liquids are finding industrial applications as green solvent systems for organic synthesis and in liquid-liquid extractions substituting more-toxic chlorinated solvents. This paper demonstrates an easy method of tuning the solubility of the poly(1-vinyl-3-alkyl-imidazolium) halides by a simple anion-exchange reaction.

引用

收藏

页码：208 / 212

页数：5

相关论文

共 15 条

[1] Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[2] Copper(I) mediated living radical polymerisation in an ionic liquid [J].

Carmichael, AJ ;

Haddleton, DM ;

Bon, SAF ;

Seddon, KR .

CHEMICAL COMMUNICATIONS, 2000, (14) :1237-1238

[3] First example of N-heterocyclic carbenes as catalysts for living polymerization:: Organocatalytic ring-opening polymerization of cyclic esters [J].

Connor, EF ;

Nyce, GW ;

Myers, M ;

Möck, A ;

Hedrick, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (06) :914-915

[4]

Freemantle M, 2003, CHEM ENG NEWS, V81, P9

[5] Use of ionic liquids for π-conjugated polymer electrochemical devices [J].

Lu, W ;

Fadeev, AG ;

Qi, BH ;

Smela, E ;

Mattes, BR ;

Ding, J ;

Spinks, GM ;

Mazurkiewicz, J ;

Zhou, DZ ;

Wallace, GG ;

MacFarlane, DR ;

Forsyth, SA ;

Forsyth, M .

SCIENCE, 2002, 297 (5583) :983-987

[6] In situ generation of carbenes:: A general and versatile platform for organocatalytic living polymerization [J].

Nyce, GW ;

Glauser, T ;

Connor, EF ;

Möck, A ;

Waymouth, RM ;

Hedrick, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (10) :3046-3056

[7] Expanding the catalytic activity of nucleophilic N-heterocyclic carbenes for transesterification reactions [J].

Nyce, GW ;

Lamboy, JA ;

Connor, EF ;

Waymouth, RM ;

Hedrick, JL .

ORGANIC LETTERS, 2002, 4 (21) :3587-3590

[8]

ROGERS RD, 2002, NATO SCI SERIES, P1

[9] Cross-linked polymer-ionic liquid composite materials [J].

Snedden, P ;

Cooper, AI ;

Scott, K ;

Winterton, N .

MACROMOLECULES, 2003, 36 (12) :4549-4556

[10] Poly(3,4-alkylenedioxythiophene)-based supercapacitors using ionic liquids as supporting electrolytes [J].

Stenger-Smith, JD ;

Webber, CK ;

Anderson, N ;

Chafin, AP ;

Zong, KK ;

Reynolds, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (08) :A973-A977