Structural investigation on implanted copper ions in silica glass by XAFS spectroscopy

被引：16

作者：

Fukumi, K

Chayahara, A

Kadono, K

Kageyama, H

Akai, T

Kitamura, N

Makihara, M

Fujii, K

Hayakawa, J

机构：

[1] Osaka National Research Institute, AIST, Ikeda, Osaka 563-8577

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1998年 / 238卷 / 1-2期

关键词：

D O I：

10.1016/S0022-3093(98)00576-6

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The chemical state and coordination state of copper ions have been studied in 2 MeV, 1 x 10(17) Cu+ ions/cm(2-)implanted silica glass by X-ray absorption fine structure spectroscopy. It was found that the implanted Cu atoms are mainly present as Cu(I) state in the glass from the comparison of X-ray absorption near edge structure spectrum of the glass with those of CuO, Cu2O, CuAlO2, CuFeO2, Ca2CuO3 and MgCu2O3 crystals. We inferred from the extended X-ray absorption fine structure spectra that the implanted Cu atoms are coordinated by two oxygen atoms and the Cu-O interatomic distance is 0.188 nm in the glass. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：143 / 151

页数：9

共 50 条

[1] ION-IMPLANTATION EFFECTS IN NONCRYSTALLINE SIO2 [J].

ARNOLD, GW .

IEEE TRANSACTIONS ON NUCLEAR SCIENCE, 1973, NS20 (06) :220-223

[2]

ASBRINK S, 1970, ACTA CRYSTALLOGR B, V29, P8

[3] CHEMICAL ASPECTS IN COPPER-IMPLANTED FUSED-SILICA AND SODA-LIME GLASSES [J].

BERTONCELLO, R ;

TRIVILLIN, F ;

CATTARUZZA, E ;

MAZZOLDI, P ;

ARNOLD, GW ;

BATTAGLIN, G ;

CATALANO, M .

JOURNAL OF APPLIED PHYSICS, 1995, 77 (03) :1294-1300

[4] A MONTE-CARLO COMPUTER-PROGRAM FOR THE TRANSPORT OF ENERGETIC IONS IN AMORPHOUS TARGETS [J].

BIERSACK, JP ;

HAGGMARK, LG .

NUCLEAR INSTRUMENTS & METHODS, 1980, 174 (1-2) :257-269

[5] STRUCTURE OF CUZR2(PO4)3 BY X-RAY AND NEUTRON POWDER DIFFRACTION [J].

BUSSEREAU, I ;

BELKHIRIA, MS ;

GRAVEREAU, P ;

BOIREAU, A ;

SOUBEYROUX, JL ;

OLAZCUAGA, R ;

LEFLEM, G .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :1741-1744

[6]

Chase Jr. M.W., 1985, J PHYS CHEM REF D S1, V14

[7] TERNARY OXOCUPRATES .9. ABOUT MGCU2O3 [J].

DRENKHAHN, H ;

MULLERBUSCHBAUM, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1975, 418 (02) :116-120

[8]

FUKUMI K, 1991, MATER RES SOC SYMP P, V201, P241

[9] FORMATION OF CUCL ULTRAFINE PARTICLES IN SILICA GLASS BY ION-IMPLANTATION [J].

FUKUMI, K ;

CHAYAHARA, A ;

KITAMURA, N ;

AKAI, T ;

HAYAKAWA, J ;

FUJII, K ;

SATOU, M .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1994, 178 (pt 2) :155-159

[10]

FUKUMI K, 1994, J AM CERAM SOC, V77, P3019, DOI 10.1111/j.1151-2916.1994.tb04539.x

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