Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η5-ligand

被引：41

作者：

Toganoh, M ^{[1
]}

Matsuo, Y ^{[1
]}

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 113, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 683卷 / 02期

基金：

日本学术振兴会;

关键词：

fullerene; Rh complex; indenyl ligand; catalysis;

D O I：

10.1016/S0022-328X(03)00465-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rhodium eta(5)-complexes bearing an indenyl-type fullerene ligand, Rh[C-60(PhCH2)(2)Ph](cod) (2), Rh[C-60(PhCH2)(2)Ph](nbd) (3) and Rh(C70Ph3)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：295 / 300

页数：6

共 36 条

[1] CYCLOTRIMERIZATION OF ACETYLENES CATALYZED BY (ETA-5-CYCLOPENTADIENYL)RHODIUM COMPLEXES [J].