Hydrotelluration of alkynes:: a unique route to Z-vinyl organometallics

被引:38
作者
Vieira, ML
Zinn, FK
Comasseto, JV
机构
[1] Univ Sao Paulo, Inst Quim, BR-05599970 Sao Paulo, Brazil
[2] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil
关键词
hydrotelluration; vinylic tellurides; transmetallation; coupling reactions; tellurium;
D O I
10.1590/S0103-50532001000500003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrotelluration reaction of alkynes is reviewed. The transformation of vinylic tellurides into reactive vinyl organometallics and the coupling reactions of vinylic tellurides with alkynes and organometallics are presented.
引用
收藏
页码:586 / 596
页数:11
相关论文
共 86 条
[21]  
Comasseto JV, 2000, ALDRICHIM ACTA, V33, P66
[22]  
COMASSETO JV, 1993, REV HETEROATOM CHEM, V9, P61
[23]   (ME3SI)3SITEH - PREPARATION, CHARACTERIZATION, AND SYNTHETIC UTILITY OF A REMARKABLY STABLE TELLUROL [J].
DABBOUSI, BO ;
BONASIA, PJ ;
ARNOLD, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :3186-3188
[24]   Selectivity on the reaction of vinylic tellurides with butyllithium in the presence of carbonyl compounds. [J].
Dabdoub, MJ ;
Jacob, RG ;
Ferreira, JTB ;
Dabdoub, VB ;
Marques, FD .
TETRAHEDRON LETTERS, 1999, 40 (40) :7159-7162
[25]   Hydrochalcogenation of phenylthioacetylenes.: Synthesis of mixed (Z)-trisubstituted 1,2-bis(organylchalcogeno)-1-alkenes [J].
Dabdoub, MJ ;
Dabdoub, VB ;
Pereira, MA .
TETRAHEDRON LETTERS, 2001, 42 (09) :1595-1597
[26]   SYNTHESIS OF (E)-VINYLIC TELLURIDES AND THEIR TRANSFORMATION INTO ALPHA,BETA-UNSATURATED ESTERS AND CARBOXYLIC-ACIDS [J].
DABDOUB, MJ ;
BEGNINI, ML ;
CASSOL, TM ;
GUERRERO, PG ;
SILVEIRA, CC .
TETRAHEDRON LETTERS, 1995, 36 (42) :7623-7626
[27]   SYNTHESIS OF VINYLIC TELLURIDES [J].
DABDOUB, MJ ;
DABDOUB, VB ;
COMASSETO, JV ;
PETRAGNANI, N .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 308 (02) :211-222
[28]   Iodocyclization of (Z)-1-(butyltelluro)-1,4-diorganylbut-1-en-3-ynes. Synthesis and reactions of 3-iodotellurophenes [J].
Dabdoub, MJ ;
Dabdoub, VB ;
Pereira, MA ;
ZukermanSchpector, J .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (26) :9503-9511
[29]   (1Z,3Z)-buta-1,3-dienyl-1-lithium species and substituted tellurophenes by Te/Li exchange on (1Z,3Z)-butyltelluro-1,3-butadienes and (1Z,3Z)-1,4-bis(butyltelluro)-1,3-butadienes. [J].
Dabdoub, MJ ;
Dabdoub, VB ;
Guerrero, PG ;
Silveira, CC .
TETRAHEDRON, 1997, 53 (12) :4199-4218
[30]   Palladium-catalyzed cross-coupling reactions of dimethyl- and diethylzinc with unsaturated organotellurium compounds [J].
Dabdoub, MJ ;
Dabdoub, VB ;
Marino, JP .
TETRAHEDRON LETTERS, 2000, 41 (04) :433-436