A molecular metal ferromagnet from the organic donor bis(ethylenedithio)tetraselenafulvalene and bimetallic oxalate complexes

被引：179

作者：

Alberola, A ^{[1
]}

Coronado, E ^{[1
]}

Galán-Mascarós, JR ^{[1
]}

Giménez-Saiz, C ^{[1
]}

Gómez-García, CJ ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol, E-46100 Burjassot, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 36期

关键词：

CHARGE-TRANSFER SALTS; II = MN; MAGNETS; FE; ANIONS; BETS; TTF; ZN; CO;

D O I：

10.1021/ja035772k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new dual-function hybrid molecular material has been obtained from the organic donor bis(ethylenedithio)tetraselenafulvalene and the honeycomb oxalate-based bimetallic network [MnCr(ox)3]-. This multilayer material consists of layers of the inorganic anionic 2D network, responsible for the appearance of ferromagnetic ordering below 5.3 K, alternating with segregated layers of the organic cation radical responsible for the transport properties: metal-like conductivity is observed from room temperature down to 150 K. Copyright © 2003 American Chemical Society.

引用

页码：10774 / 10775

页数：2

共 18 条

[11] LYUBOVSKAYA RN, 1987, JETP LETT+, V46, P188
[12] CRYSTAL-STRUCTURES AND PHYSICAL-PROPERTIES OF BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE CHARGE-TRANSFER SALTS WITH FECL4-ANIONS OR FEBR4-ANIONS
MALLAH, T
HOLLIS, C
BOTT, S
KURMOO, M
DAY, P
ALLAN, M
FRIEND, RH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03): : 859 - 865
[13] Miller J.S., 1990, ADV MATER, V2, P98
[14] ORGANIC CONDUCTORS WITH 3-COMPONENT SYSTEM CONTAINING CO, ZN, AND CD BASED UPON BEDT-TTF
MORI, H
HIRABAYASHI, I
TANAKA, S
MORI, T
MARUYAMA, Y
[J]. SYNTHETIC METALS, 1995, 70 (1-3) : 789 - 790
[15] Modeling stacking faults in the layered molecular-based magnets AMIIFe(C2O4)3 {MII = Mn, Fe; A = organic cation}
Nuttall, CJ
Day, P
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1999, 147 (01) : 3 - 10
[16] Molecular-based magnetism in bimetallic two-dimensional oxalate-bridged networks. An X-ray and neutron diffraction study
Pellaux, R
Schmalle, HW
Huber, R
Fischer, P
Hauss, T
Ouladdiaf, B
Decurtins, S
[J]. INORGANIC CHEMISTRY, 1997, 36 (11) : 2301 - 2308
[17] Shibaeva R. P., 1988, Soviet Physics - Crystallography, V33, P834
[18] DESIGN OF METAL-COMPLEX MAGNETS - SYNTHESES AND MAGNETIC-PROPERTIES OF MIXED-METAL ASSEMBLIES (NBU4[MCR(OX)3])X (NBU4+=TETRA(NORMAL-BUTYL)AMMONIUM ION OX(2-)= OXALATE ION M=MN2+,FE2+,CO2+,NI2+,CU2+,ZN2+)
TAMAKI, H
ZHONG, ZJ
MATSUMOTO, N
KIDA, S
KOIKAWA, M
ACHIWA, N
HASHIMOTO, Y
OKAWA, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (18) : 6974 - 6979

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