Carbon dioxide inclusion phases of a transformable 1D coordination polymer host [Rh2(O2CPh)4(pyz)]n

被引：222

作者：

Takamizawa, S ^{[1
]}

Nakata, E

Yokoyama, H

Mochizuki, K

Mori, W

机构：

[1] Yokohama City Univ, Grad Sch Integrated Sci, Kanazawa Ku, Yokohama, Kanagawa 2360027, Japan

[2] Kanagawa Univ, Fac Sci, Dept Chem, Hiratsuka, Kanagawa 2591293, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 36期

关键词：

adsorption; host-guest systems; inclusion compounds; phase transitions; X-ray diffraction;

D O I：

10.1002/anie.200351368

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CO2 is included: The one-dimensional coordination polymer host [Rh2(O2CPh)4(pyz)]n (pyz = pyrazine; see picture, left) undergoes a reversible phase transition under cooling that is induced by CO2, adsorption to give an inclusion complex, in which up to three CO2 molecules per polymer unit reside within channels (right).

引用

页码：4331 / 4334

页数：4

共 20 条

[1]

Atwood J. L., 1991, INCLUSION COMPOUNDS

[2] Guest transport in a nonporous organic solid via dynamic van der Waals cooperativity [J].