Triaquabis(nitrato-O,O′)(2,2′:6′,2"-terpyridine-κ3N)gadalinium(III) nitrate

被引：17

作者：

Leverd, PC

Charbonnel, MC

Dognon, JP

Lance, M

Nierlich, M

机构：

[1] CEA Saclay, SCM, CNRS, URA 331, F-91191 Gif Sur Yvette, France

[2] CEA, VALRHO Marcoule, DCC,DRDD, SEMP,LCTS, F-30207 Bagnols Sur Ceze, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198013316

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gadolinium nitrate forms a complex with terpyridine at the interface between an aqueous solution of the metal cation and a chloroform solution of the organic ligand. The title complex, [Gd(terpy)(NO3)(2)(H2O)(3)]NO3 (terpy = terpyridine, C15H11N3), is ten-coordinate and its coordination polyhedron can be described as a distorted bicapped square antiprism. The coordinated nitrates are bidentate. The three water ligands form hydrogen bonds in the lattice.

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页码：368 / 370

页数：3

相关论文

共 14 条

[1] COMPLEXES OF LANTHANIDE IONS WITH THE CROWN ETHER 1,4,7,10,13,16-HEXAOXACYCLO-OCTADECANE [J].

BACKERDIRKS, JDJ ;

COOKE, JE ;

GALAS, AMR ;

GHOTRA, JS ;

GRAY, CJ ;

HART, FA ;

HURSTHOUSE, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (11) :2191-2198

[2]

*BRUK AN XRAY SYST, 1997, SHELXTL REL 5

[3] THE 1ST EXAMPLE OF A MONO-HELICAL COMPLEX OF 2,2'/6',2''/6'',2'''/6''',2''''/6'''',2'''''-SEXIPYRIDINE - PREPARATION, CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(NITRATO-O,O') (2,2'/6',2''/6'',2'''/6''',2''''/6'''',2'''''-SEXIPYRIDINE)EUROPIUM(III)NITRATE [J].

CONSTABLE, EC ;

CHOTALIA, R ;

TOCHER, DA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (10) :771-773

[4] X-RAY AND MULTINUCLEAR MAGNETIC-RESONANCE STUDY OF THE COMPLEXES OF LANTHANUM(III) WITH 2,2'/6',2''-TERPYRIDINE [J].

FRECHETTE, M ;

BENSIMON, C .

INORGANIC CHEMISTRY, 1995, 34 (13) :3520-3527

[5] CRYSTAL STRUCTURE OF TRIS-(2,2',6',2''-TERPYRIDYL)EUROPEIUM(3) PERCHLORATE [J].

FROST, GH ;

HART, FA ;

HEATH, C ;

HURSTHOUSE, MB .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (23) :1421-+

[6] STRUCTURE AND STEREOCHEMISTRY IN F-BLOCK COMPLEXES OF HIGH COORDINATION-NUMBER .8. THE [M(UNIDENTATE)9] SYSTEM - CRYSTAL-STRUCTURES OF [M(OH2)9] [CF3SO3]3, M = LA, GD, LU, Y [J].

HARROWFIELD, JM ;

KEPERT, DL ;

PATRICK, JM ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1983, 36 (03) :483-492

[7]

HOLTZ RC, 1988, INORG CHEM, V27, P4640

[8] STRUCTURAL SYSTEMATICS OF RARE-EARTH COMPLEXES .5. THE HYDRATED 1/1 ADDUCTS OF 2,2'/6',2''-TERPYRIDINE WITH THE LANTHANOID(III) CHLORIDES [J].

KEPERT, CJ ;

LU, WM ;

SKELTON, BW ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1994, 47 (02) :365-384

[9] CONFORMATIONAL PROPERTIES OF EU(III) COMPLEXES OF 3,3'-5,3''-POLYMETHYLENE BRIDGED DERIVATIVES OF 2,2'-6,2''-TERPYRIDINE [J].

MALLET, C ;

THUMMEL, RP ;

HERY, C .

INORGANICA CHIMICA ACTA, 1993, 210 (02) :223-231

[10] Processing of X-ray diffraction data collected in oscillation mode [J].

Otwinowski, Z ;

Minor, W .

MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 :307-326