Triaquabis(nitrato-O,O′)(2,2′:6′,2"-terpyridine-κ3N)gadalinium(III) nitrate

被引：17

作者：

Leverd, PC

Charbonnel, MC

Dognon, JP

Lance, M

Nierlich, M

机构：

[1] CEA Saclay, SCM, CNRS, URA 331, F-91191 Gif Sur Yvette, France

[2] CEA, VALRHO Marcoule, DCC,DRDD, SEMP,LCTS, F-30207 Bagnols Sur Ceze, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198013316

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gadolinium nitrate forms a complex with terpyridine at the interface between an aqueous solution of the metal cation and a chloroform solution of the organic ligand. The title complex, [Gd(terpy)(NO3)(2)(H2O)(3)]NO3 (terpy = terpyridine, C15H11N3), is ten-coordinate and its coordination polyhedron can be described as a distorted bicapped square antiprism. The coordinated nitrates are bidentate. The three water ligands form hydrogen bonds in the lattice.

引用

页码：368 / 370

页数：3