Carbometalation of unactivated alkenes by zinc enolate derivatives

被引：30

作者：

Perez-Luna, Alejandro ^{[1
]}

Botuha, Candice ^{[1
]}

Ferreira, Franck ^{[1
]}

Chemla, Fabrice ^{[1
]}

机构：

[1] Univ Paris 06, UPMC, Chim Organ Lab, UMR 7611,FR 2769, F-75252 Paris 05, France

来源：

NEW JOURNAL OF CHEMISTRY | 2008年 / 32卷 / 04期

关键词：

D O I：

10.1039/b716292h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The carbometalation reaction of zinc enolates and related stabilised organometallics on unactivated double bonds has emerged over the past decade as a mechanistically interesting and synthetically useful reaction. This Perspective is devoted to these challenging and apparently contra-thermodynamic transformations, with a special focus on recent mechanistic considerations involving radical-polar crossover reaction pathways.

引用

页码：594 / 606

页数：13

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