Diethylzinc: A chain-transfer agent in intermolecular radical additions. A parallel with triethylborane

被引：105

作者：

Bertrand, MP ^{[1
]}

Feray, L ^{[1
]}

Nouguier, R ^{[1
]}

Perfetti, P ^{[1
]}

机构：

[1] Univ Aix Marseille 3, Fac Sci St Jerome, UMR 6517, Lab Chim Mol Organ, F-13397 Marseille 20, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1999年 / 64卷 / 25期

关键词：

D O I：

10.1021/jo9912404

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of oxygen, diethylzinc can be used to promote radical additions to C=N bond containing radical accepters and to enones. In these reactions, it plays at the same time the role of the initiator and the role of the chain-transfer reagent. A parallel with triethylborane-mediated reactions is established. The methodology is restricted to secondary and tertiaryalkyl radicals generated from the corresponding alkyl iodides. It could not be extended either to C=C bond containing radical accepters such as methyl methacrylate and nitrocyclohexene or to diethylazodicarboxylate.

引用

页码：9189 / 9193

页数：5

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