Submicron and nanostructured 0.8Pb(Mg1/3Nb2/3)O3-0.2PbTiO3 ceramics by hot pressing of nanocrystalline powders

被引:15
作者
Amorin, H. [1 ]
Ricote, J. [1 ]
Jimenez, R. [1 ]
Holc, J. [2 ]
Kosec, M. [2 ]
Alguero, M. [1 ]
机构
[1] CSIC, Inst Ciencia Mat, Madrid 28049, Spain
[2] Jozef Stefan Inst, Ljubljana 1000, Slovenia
关键词
ferroelectricity; functional ceramics; mechanosynthesis; hot pressing; microstructure;
D O I
10.1016/j.scriptamat.2007.12.015
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Nanocrystalline powders synthesized by mechanochemical activation were successfully used to process high-density submicron- and nanostructured 0.8Pb(Mg1/3Nb2/3)O-3-0.2PbTiO(3) perovskite phase ceramics by hot pressing, with average grain size ranging from 0.36 mu m down to 88 nm. These materials are very suitable for studying the size dependence of the properties across the submicron range approaching the nanoscale. This is the first report of such a series of ceramic materials of a relaxor-based morphotropic phase boundary composition, and of its properties as a function of the grain size. (C) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:755 / 758
页数:4
相关论文
共 21 条
[1]   Size effect in morphotropic phase boundary Pb(Mg1/3Nb2/3)O3-PbTiO3 [J].
Alguero, M. ;
Ricote, J. ;
Jimenez, R. ;
Ramos, P. ;
Carreaud, J. ;
Dkhil, B. ;
Kiat, J. M. ;
Holc, J. ;
Kosec, M. .
APPLIED PHYSICS LETTERS, 2007, 91 (11)
[2]   High-sensitivity piezoelectric, low-tolerance-factor perovskites by mechanosynthesis [J].
Alguero, M. ;
Ricote, J. ;
Hungria, T. ;
Castro, A. .
CHEMISTRY OF MATERIALS, 2007, 19 (20) :4982-4990
[3]   Processing by mechano synthesis and properties of piezoelectric Pb(Mg1/3Nb2/3)O3-PbTiO3 with different compositions [J].
Algueró, M ;
Moure, A ;
Pardo, L ;
Holc, J ;
Kosec, M .
ACTA MATERIALIA, 2006, 54 (02) :501-511
[4]   Piezoelectric PMN-PT ceramics from mechanochemically activated precursors [J].
Algueró, M ;
Alemany, C ;
Jiménez, B ;
Holc, J ;
Kosec, M ;
Pardo, L .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2004, 24 (06) :937-940
[5]   Relaxor behavior, polarization buildup, and switching in nanostructured 0.92 PbZn1/3Nb2/3O3-0.08 PbTiO3 ceramics [J].
Alguero, Miguel ;
Hungria, Teresa ;
Amorin, Harvey ;
Ricote, Jesus ;
Galy, Jean ;
Castro, Alicia .
SMALL, 2007, 3 (11) :1906-1911
[6]   High dielectric constant and frozen macroscopic polarization in dense nanocrystalline BaTiO3 ceramics [J].
Buscaglia, MT ;
Viviani, M ;
Buscaglia, V ;
Mitoseriu, L ;
Testino, A ;
Nanni, P ;
Zhao, Z ;
Nygren, M ;
Harnagea, C ;
Piazza, D ;
Galassi, C .
PHYSICAL REVIEW B, 2006, 73 (06)
[7]   Monoclinic morphotropic phase and grain size-induced polarization rotation in Pb(Mg1/3Nb2/3)O3-PbTiO3 [J].
Carreaud, J. ;
Kiat, J. M. ;
Dkhil, B. ;
Alguero, M. ;
Ricote, J. ;
Jimenez, R. ;
Holc, J. ;
Kosec, M. .
APPLIED PHYSICS LETTERS, 2006, 89 (25)
[8]   Size-driven relaxation and polar states in PbMg1/3Nb2/3O3-based system -: art. no. 174115 [J].
Carreaud, J ;
Gemeiner, P ;
Kiat, JM ;
Dkhil, B ;
Bogicevic, C ;
Rojac, T ;
Malic, B .
PHYSICAL REVIEW B, 2005, 72 (17)
[9]   Nanocrystalline materials prepared through crystallization by ball milling [J].
Giri, AK .
ADVANCED MATERIALS, 1997, 9 (02) :163-166
[10]   Enhancement of p-type conductivity, in nanocrystalline BaTiO3 ceramics -: art. no. 082110 [J].
Guo, X ;
Pithan, C ;
Ohly, C ;
Jia, CL ;
Dornseiffer, J ;
Haegel, FH ;
Waser, R .
APPLIED PHYSICS LETTERS, 2005, 86 (08) :1-3