Aqua(5,6-dimethyl-1,10-phenanthroline-N,N′)(malonato-O,O′)copper(II) hydrate

被引:13
作者
Gasque, L [1 ]
Moreno-Esparza, R
Mollins, E
Briansó-Penalva, JL
Ruiz-Ramírez, L
Medina-Dickinson, G
机构
[1] Univ Nacl Autonoma Mexico, Fac Quim, Dept Quim Inorgan, Mexico City 04510, DF, Mexico
[2] Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain
[3] Univ Autonoma Barcelona, Unidad Cristalog, Bellaterra 08193, Spain
关键词
D O I
10.1107/S0108270198009937
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Each copper ion in the title complex, [Cu(C3H2O4)(C14H12N2)(H2O)]. H2O, displays a slightly distorted square-pyramidal coordination geometry, where the water molecule is in the apical position and two malonate O atoms and the phenanthroline N atoms define the base. The five-membered chelate ring defined by the phenanthroline molecule and the Cu atom is nearly planar with only slight distortion, while the ring defined by the malonate moiety and the Cu atom displays an envelope conformation. Hydrogen-bond and pi-pi* interactions define the crystal packing.
引用
收藏
页码:158 / 160
页数:3
相关论文
共 14 条
[1]  
BORGHI F, 1987, GAZZ CHIM ITAL, V117, P557
[2]   SYNTHESIS AND STRUCTURAL STUDIES OF TETRAAQUACOPPER(II) DIAQUABIS(MALONATO)CUPRATE(II) [J].
CHATTOPADHYAY, D ;
CHATTOPADHYAY, SK ;
LOWE, PR ;
SCHWALBE, CH ;
MAZUMDER, SK ;
RANA, A ;
GHOSH, S .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (06) :913-916
[3]  
ENRAFNONIUS, 1989, CAD4 SOFTWARE VERSIO
[4]  
FAIR CK, 1990, MOLEN INTERACTIVE IN
[5]  
HAMALAINEN R, 1973, SUOM KEMISTIL, V46, P285
[6]  
KANSIKAS J, 1977, FINN CHEM LETT, P118
[7]   OXAMIDE OXIME-BASED COPPER(II) COORDINATION POLYMERS - 2-DIMENSIONAL AND 3-DIMENSIONAL STRUCTURES CONTROLLED BY DICARBOXYLATES [J].
KAWATA, S ;
KITAGAWA, S ;
MACHIDA, H ;
NAKAMOTO, T ;
KONDO, M ;
KATADA, M ;
KIKUCHI, K ;
IKEMOTO, I .
INORGANICA CHIMICA ACTA, 1995, 229 (1-2) :211-219
[8]   THERMAL, SPECTROSCOPIC, AND STRUCTURAL-PROPERTIES OF AQUA(MALONATO-O,O') (1,10-PHENANTHROLINE)COPPER(II) HYDRATE (1/1.5) [J].
KWIK, WL ;
ANG, KP ;
CHAN, HSO ;
CHEBOLU, V ;
KOCH, SA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (12) :2519-2523
[9]   A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].
NORTH, ACT ;
PHILLIPS, DC ;
MATHEWS, FS .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&
[10]  
PAJUNEN A, 1977, FINN CHEM LETT, P100