Bifunctional metal-ligand catalysis:: Hydrogenations and new reactions within the metal-(di)amine scaffold

被引：107

作者：

Muñiz, K ^{[1
]}

机构：

[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 41期

关键词：

diamines; homogeneous catalysis; hydrogenation; reduction; transition metals;

D O I：

10.1002/anie.200501787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No metal-substrate interactions: A transition-metal complex of a primary amine can serve as an efficient bifunctional metal-ligand catalyst that functions without direct interaction of the metal and the substrate. The example shows the transition-state structure of the enantioselective reduction of acetophenone at the molecular surface of a ruthenium hydride complex bearing a diamine with one free NH2 group (O red, Ru green, N blue). (Figure Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6622 / 6627

页数：6

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