Structural properties of the graphene-SiC(0001) interface as a key for the preparation of homogeneous large-terrace graphene surfaces

被引:313
作者
Riedl, C. [1 ]
Starke, U. [1 ]
Bernhardt, J. [2 ]
Franke, M. [2 ]
Heinz, K. [2 ]
机构
[1] Max Planck Inst Festkorperforschung, D-70569 Stuttgart, Germany
[2] Univ Erlangen Nurnberg, Lehrstuhl Festkorperphys, D-91058 Erlangen, Germany
关键词
D O I
10.1103/PhysRevB.76.245406
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report on the interface between graphene and 4H-SiC(0001) as investigated by scanning tunneling microscopy (STM) and low energy electron diffraction (LEED). It is characterized by the so-called (6 root 3 X 6 root 3) R30 degrees reconstruction, whose structural properties are still controversially discussed but at the same time are crucial for the controlled growth of homogeneous high-quality large-terrace graphene surfaces. We discuss the role of three observed phases with periodicities (6 root 3 X 6 root 3)R30 degrees, (6 X 6), and (5 X 5). Their LEED intensity levels and spectra strongly depend on the surface preparation procedure applied. The graphitization process imprints distinct features in the STM images as well as in the LEED spectra. The latter have the potential for an easy and practicable determination of the number of graphene layers by means of LEED.
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页数:8
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共 35 条
[1]   Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[2]   Epitaxially ideal oxide-semiconductor interfaces: Silicate adlayers on hexagonal (0001) and (000(1)over-bar) SiC surfaces [J].
Bernhardt, J ;
Schardt, J ;
Starke, U ;
Heinz, K .
APPLIED PHYSICS LETTERS, 1999, 74 (08) :1084-1086
[3]   Solid-state decomposition of silicon carbide for growing ultra-thin heteroepitaxial graphite films [J].
Charrier, A ;
Coati, A ;
Argunova, T ;
Thibaudau, F ;
Garreau, Y ;
Pinchaux, R ;
Forbeaux, I ;
Debever, JM ;
Sauvage-Simkin, M ;
Themlin, JM .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (05) :2479-2484
[4]   Atomic structure of the 6H-SiC(0001) nanomesh [J].
Chen, W ;
Xu, H ;
Liu, L ;
Gao, XY ;
Qi, DC ;
Peng, GW ;
Tan, SC ;
Feng, YP ;
Loh, KP ;
Wee, ATS .
SURFACE SCIENCE, 2005, 596 (1-3) :176-186
[5]   Epitaxial graphene [J].
de Heer, Walt A. ;
Berger, Claire ;
Wu, Xiaosong ;
First, Phillip N. ;
Conrad, Edward H. ;
Li, Xuebin ;
Li, Tianbo ;
Sprinkle, Michael ;
Hass, Joanna ;
Sadowski, Marcin L. ;
Potemski, Marek ;
Martinez, Gerard .
SOLID STATE COMMUNICATIONS, 2007, 143 (1-2) :92-100
[6]   Initial stages of the Graphite-SiC(0001) interface formation studied by photoelectron Spectroscopy [J].
Emtsev, K. V. ;
Seyller, Th. ;
Speck, F. ;
Ley, L. ;
Stojanov, P. ;
Riley, J. D. ;
Leckey, R. G. C. .
SILICON CARBIDE AND RELATED MATERIALS 2006, 2007, 556-557 :525-+
[7]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[8]   Heteroepitaxial graphite on 6H-SiC(0001):: Interface formation through conduction-band electronic structure [J].
Forbeaux, I ;
Themlin, JM ;
Debever, JM .
PHYSICAL REVIEW B, 1998, 58 (24) :16396-16406
[9]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[10]   Field effect in epitaxial graphene on a silicon carbide substrate [J].
Gu, Gong ;
Nie, Shu ;
Feenstra, R. M. ;
Devaty, R. P. ;
Choyke, W. J. ;
Chan, Winston K. ;
Kane, Michael G. .
APPLIED PHYSICS LETTERS, 2007, 90 (25)