Fluctuation effects in ternary AB+A+B polymeric emulsions

被引:124
作者
Düchs, D
Ganesan, V
Fredrickson, GH
Schmid, F
机构
[1] Univ Bielefeld, Fak Phys, D-33615 Bielefeld, Germany
[2] Univ Texas, Dept Chem Engn, Austin, TX 78712 USA
[3] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA
[4] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA
基金
美国国家科学基金会;
关键词
D O I
10.1021/ma030201y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We present a Monte Carlo approach to incorporating the effect of thermal fluctuations in field theories of polymeric fluids. This method is applied to a field-theoretic model of a ternary blend of AB diblock copolymers with A and B homopolymers. We find a shift in the line of order-disorder transitions from their mean-field values, as well as strong signatures of the existence of a bicontinuous microemulsion phase in the vicinity of the mean-field Lifshitz critical point. This is in qualitative agreement with a recent series of experiments conducted with various three-dimensional realizations of this model system. Further, we also compare our results and the performance of the presently proposed simulation method to that of an alternative method involving the integration of complex Langevin dynamical equations.
引用
收藏
页码:9237 / 9248
页数:12
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