Binap and MeO-Biphep complexes of Ru(II). Dicationic ligands as 6e donors. Unexpected cyclometallation in connection with P-C bond breaking

被引：30

作者：

den Reijer, CJ

Dotta, P

Pregosin, PS ^{[1
]}

Albinati, A

机构：

[1] ETH Zurich, Inorgan Chem Lab, CH-8092 Zurich, Switzerland

[2] Univ Milan, Inst Pharmaceut Chem, I-20131 Milan, Italy

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2001年 / 79卷 / 5-6期

关键词：

P-C bond cleavage; 6e donors; cyclometallation; hydrides; C-13; NMR;

D O I：

10.1139/cjc-79-5-6-693

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of cationic and dicationic Ru-arene complexes with Binap (1a) and MeO-Biphep (1b) have been prepared. C-13 NMR studies are shown to be useful in connection with recognising the 6e-bonding mode of 1a and 1b in the dications [Ru(1a or 1b)(eta (6)-arene)](SbF6)(2) (8,9). Reaction of 8,9 with: (a) (Bu4N)(Ph3SiF2) leads to a cyclometallated product which arises via P-C bond breaking and P-F bond making; (b) methanol provides a straightforward synthesis of the corresponding hydrides. C-13 NMR p-cymene chemical shifts are reported.

引用

页码：693 / 704

页数：12

共 44 条

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