Enantioselective amino acid synthesis by chiral phase-transfer catalysis

被引：779

作者：

Maruoka, K ^{[1
]}

Ooi, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 08期

关键词：

D O I：

10.1021/cr020020e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantioselective synthesis of α-amino acids was greatly advanced by the creation of new chiral phase-transfer catalysts, which maximize the characteristic features of the central quaternary ammonium cations. Indeed, such phase-transfer-catalyzed enatioselective syntheses of α-amino acids were very useful in practical synthesis, and their applications were illustrated in numerous papers. This paper describes the enantioselective reactions which clearly demonstrate the high ability and great potential of chiral phase-transfer catalysis to synthesize various types of chiral α-amino acid derivatives.

引用

页码：3013 / 3028

页数：16

共 104 条

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