Determination of micelle structure of octyI-β-glucoside in aqueous solution by small angle neutron scattering and geometric analysis

被引：34

作者：

He, LZ

Garamus, V

Niemeyer, B ^{[1
]}

Helmholz, H

Willumeit, R

机构：

[1] GKSS Forschungszentrum Geesthacht GmbH, Inst Phys & Chem Anal, D-21502 Geesthacht, Germany

[2] GKSS Forschungszentrum Geesthacht GmbH, Mat Res Inst, D-21502 Geesthacht, Germany

[3] Univ Fed Armed Forces, Inst Thermodynam, D-22043 Hamburg, Germany

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2000年 / 89卷 / 1-3期

关键词：

D O I：

10.1016/S0167-7322(00)90017-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Small angle neutron scattering (SANS) experiments were performed to investigate the structure of micelle of n-octyl-beta -glucoside, Ellipsoidal and cylindrical models were applied to fit SANS data. It was found that the models can describe the scattering data fairly well. Aggregation number and molecular structure of n-octyl-beta -glucoside as well as SANS data were taken into account to analyse micelle structure. The hydrodynamic radius predicted by the cylindrical model was consistent with that obtained from diffusivity by other authors. This suggests that the obtained shape of micelle is reasonable. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：239 / 248

页数：10

共 31 条

[1] SOLUTION PROPERTIES OF OCTYL-BETA-D-GLUCOSIDE .2. THERMODYNAMICS OF MICELLE FORMATION [J].