High performance Ge nanowire anode sheathed with carbon for lithium rechargeable batteries

被引:260
作者
Seo, Min-Ho [1 ]
Park, Mihee [1 ]
Lee, Kyu Tae [1 ]
Kim, Kitae [2 ]
Kim, Jeyoung [2 ]
Cho, Jaephil [1 ]
机构
[1] Ulsan Natl Inst Sci & Technol, Interdisciplinary Sch Green Energy, Ulsan 689798, South Korea
[2] LG Chem Ltd, Taejon 305380, South Korea
关键词
GERMANIUM NANOCRYSTALS; CAPACITY; NANOPARTICLES; ELECTRODES; PARTICLES; STORAGE; HOLLOW;
D O I
10.1039/c0ee00552e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We present a single crystalline Ge nanowire anode material sheathed with carbon prepared by a solid-liquid solution method. The composite electrode composed of Ge nanowires shows impressive electrochemical properties, exhibiting a very high reversible charge capacity (after lithium removal) of 963 mA h g(-1) with a coulombic efficiency of 91%.
引用
收藏
页码:425 / 428
页数:4
相关论文
共 46 条
[1]   Lithium-ion intercalation into TiO2-B nanowires [J].
Armstrong, AR ;
Armstrong, G ;
Canales, J ;
García, R ;
Bruce, PG .
ADVANCED MATERIALS, 2005, 17 (07) :862-+
[2]   Nanoparticles of SnO produced by sonochemistry as anode materials for rechargeable lithium batteries [J].
Aurbach, D ;
Nimberger, A ;
Markovsky, B ;
Levi, E ;
Sominski, E ;
Gedanken, A .
CHEMISTRY OF MATERIALS, 2002, 14 (10) :4155-4163
[3]   QUANTITATIVE STUDY ON GROWTH OF SILICON WHISKERS FROM SILANE AND GERMANIUM WHISKERS FROM GERMANE [J].
BOOTSMA, GA ;
GASSEN, HJ .
JOURNAL OF CRYSTAL GROWTH, 1971, 10 (03) :223-&
[4]   High capacity Li ion battery anodes using Ge nanowires [J].
Chan, Candace K. ;
Zhang, Xiao Feng ;
Cui, Yi .
NANO LETTERS, 2008, 8 (01) :307-309
[5]   High-performance lithium battery anodes using silicon nanowires [J].
Chan, Candace K. ;
Peng, Hailin ;
Liu, Gao ;
McIlwrath, Kevin ;
Zhang, Xiao Feng ;
Huggins, Robert A. ;
Cui, Yi .
NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35
[6]   Porous Si anode materials for lithium rechargeable batteries [J].
Cho, Jaephil .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (20) :4009-4014
[7]   Seeded germanium nanowire synthesis in solution [J].
Chockla, Aaron M. ;
Korgel, Brian A. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (07) :996-1001
[8]   A Germanium-Carbon Nanocomposite Material for Lithium Batteries [J].
Cui, Guanglei ;
Gu, Lin ;
Zhi, Linjie ;
Kaskhedikar, N. ;
van Aken, Peter A. ;
Muellen, Klaus ;
Maier, Joachim .
ADVANCED MATERIALS, 2008, 20 (16) :3079-3083
[9]   Crystalline-Amorphous Core-Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes [J].
Cui, Li-Feng ;
Ruffo, Riccardo ;
Chan, Candace K. ;
Peng, Hailin ;
Cui, Yi .
NANO LETTERS, 2009, 9 (01) :491-495
[10]   Green energy storage materials: Nanostructured TiO2 and Sn-based anodes for lithium-ion batteries [J].
Deng, Da ;
Kim, Min Gyu ;
Lee, Jim Yang ;
Cho, Jaephil .
ENERGY & ENVIRONMENTAL SCIENCE, 2009, 2 (08) :818-837