Electrochemical control of the photocurrent direction in intercalated DNA/CdS nanoparticle systems

被引:122
作者
Gill, R [1 ]
Patolsky, F [1 ]
Katz, E [1 ]
Willner, I [1 ]
机构
[1] Hebrew Univ Jerusalem, Inst Chem, IL-91904 Jerusalem, Israel
关键词
DNA; electrochemistry; intercalations; nanostructures; semiconductors;
D O I
10.1002/anie.200500830
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) A change in direction: The photocurrent generated by CdS nanoparticles attached by means of a double-stranded DNA linker to a gold electrode is reversibly switched between the anodic or cathodic direction (see graphic) depending on the redox state of the methylene blue inter-calator. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4554 / 4557
页数:4
相关论文
共 28 条
[1]   Bi-directional photocurrent generation dependent on the wavelength of irradiation of a mixed monolayer assembly [J].
Akiyama, T ;
Nitahara, S ;
Inoue, S ;
Yamada, S .
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2004, 3 (01) :26-28
[2]   Molecular logic circuits [J].
Balzani, V ;
Credi, A ;
Venturi, M .
CHEMPHYSCHEM, 2003, 4 (01) :49-59
[3]  
BODNARCHUK MI, 2004, THEOR EXP CHEM, V40, P287, DOI DOI 10.1023/B:THEC.0000049074.31907.81
[4]   Absence of dc-conductivity in λ-DNA [J].
de Pablo, PJ ;
Moreno-Herrero, F ;
Colchero, J ;
Gomez-Herrero, J ;
Herrero, P ;
Baró, AM ;
Ordejón, P ;
Soler, JM ;
Artacho, E .
PHYSICAL REVIEW LETTERS, 2000, 85 (23) :4992-4995
[5]   Molecular-scale logic gates [J].
de Silva, AP ;
McClenaghan, ND .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (03) :574-586
[6]   Molecular computation - Molecular logic gets loaded [J].
De Silva, AP .
NATURE MATERIALS, 2005, 4 (01) :15-16
[7]  
Demeunynck M., 2004, Small Molecule DNA and RNA Binders: From Synthesis to Nucleic Acid Complexes
[8]   Electrochemical DNA sensors [J].
Drummond, TG ;
Hill, MG ;
Barton, JK .
NATURE BIOTECHNOLOGY, 2003, 21 (10) :1192-1199
[9]   A nanometre-scale electronic switch consisting of a metal cluster and redox-addressable groups [J].
Gittins, DI ;
Bethell, D ;
Schiffrin, DJ ;
Nichols, RJ .
NATURE, 2000, 408 (6808) :67-69
[10]   Electrochemical assembly of a CdS semiconductor nanoparticle monolayer on surfaces: Structural properties and photoelectrochemical applications [J].
Granot, E ;
Patolsky, F ;
Willner, I .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (19) :5875-5881